Coke activation method involves treating coke with a solution of an oxidising agent in sulphuric acid
2024-01-19
专利权人GAZPROM NEFT STOCK CO (GZPM-C)
申请日期2024-01-19
专利号RU2832352-C1
成果简介NOVELTY - Invention relates to the technology of producing carbon materials with a developed surface and porosity, in particular to a method for activating coke. Method involves treating coke with a solution of an oxidising agent in sulphuric acid, diluting the reaction mixture with water, washing to weakly acidic pH, drying and activating the dried oxidised coke with potassium hydroxide. Oxidising agent used is ammonium persulphate, and the sulphuric acid used is sulphuric acid with H2SO4 content of 98-100%. Oxidation is carried out with gradual addition of ammonium persulphate to a suspension of coke in sulphuric acid and while cooling the reaction mixture, wherein ammonium persulphate is added at such a rate that the temperature of the reaction mixture is maintained within range of 40 to 50 °C. Oxidised coke is washed with diluted aqueous solution of nitric acid with pH 2.5-3. Prior to activation, dried oxidised coke is subjected to heat treatment at 500 °C. USE - Performing operations. ADVANTAGE - Obtaining activated carbons with high specific surface area and porosity by changing the nature of the oxidant and selecting process modes of oxidation, which enables to eliminate release of very toxic vapours. 4 cl, 1 tbl, 10 ex
IPC 分类号B01J-020/30 ; C01B-032/312
国家俄罗斯
专业领域化学化工
语种英语
成果类型专利
文献类型科技成果
条目标识符http://119.78.100.226:8889/handle/3KE4DYBR/18394
专题中国科学院新疆生态与地理研究所
作者单位
GAZPROM NEFT STOCK CO (GZPM-C)
推荐引用方式
GB/T 7714
MELEZHIK A V,MEMETOV N R,BURAKOV A E,et al. Coke activation method involves treating coke with a solution of an oxidising agent in sulphuric acid. RU2832352-C1[P]. 2024.
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