CATALYST FOR HYDROGENATION OF BENZENE AND ITS HOMOLOGUES
2024-06-06
专利权人FEDERAL STATE BUDGETARY EDUCATIONAL (BUDG-Non-standard)
申请日期2024-06-06
专利号RU2830160-C1
成果简介NOVELTY - Invention relates to catalysts for reducing an aromatic ring and can be used in organic synthesis. Catalyst for hydrogenation of benzene and its homologues consists of nanostructured nickel particles immobilized on gamma-aluminium oxide. Nickel nanoparticles are deposited by impregnation of gamma-aluminium oxide while boiling in a solution of nickel chloride hexahydrate and carbamide in 7 wt.% aqueous ammonia solution, followed by addition of boric acid. Weight ratio of γ-Al2O3, nickel chloride hexahydrate, carbamide, boric acid is equal to 1:2:2.4:0.6, respectively. Adsorbed nickel chloride is reduced at temperature of 80-100 °C for 1 hour with mixture of 0.025 wt.% aqueous solution of sodium borohydride and hydrazine monohydrate, taken in molar ratio of 4:3. USE - Chemistry. ADVANTAGE - Invention enables to obtain an efficient hydrogenation catalyst with high specific output and stability. 1 cl, 1 tbl
IPC 分类号B01J-021/04 ; B01J-023/755 ; B01J-037/02 ; B01J-037/08 ; B01J-037/18 ; B82Y-030/00 ; C07C-005/10
国家俄罗斯
专业领域化学化工
语种英语
成果类型专利
文献类型科技成果
条目标识符http://119.78.100.226:8889/handle/3KE4DYBR/16376
专题中国科学院新疆生态与地理研究所
作者单位
FEDERAL STATE BUDGETARY EDUCATIONAL (BUDG-Non-standard)
推荐引用方式
GB/T 7714
MOKHOV V M,NEBYKOV D N,ANTONOVA P E,et al. CATALYST FOR HYDROGENATION OF BENZENE AND ITS HOMOLOGUES. RU2830160-C1[P]. 2024.
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